(2,2′-Dimethyl-4,4′-bi-1,3-thiazole-κ2 N,N′)bis(thiocyanato-κS)mercury(II)
نویسندگان
چکیده
The Hg(II) atom in the title compound, [Hg(SCN)(2)(C(8)H(8)N(2)S(2))], is chelated by the bidentate heterocycle through the N atoms and is coordinated by the S atoms of two thiocyanate anions, resulting in a considerably distorted tetra-hedral coordination geometry.
منابع مشابه
(2,2′-Dimethyl-4,4′-bi-1,3-thiazole-κ2 N,N′)diiodidomercury(II)
In the title compound, [HgI(2)(C(8)H(8)N(2)S(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bithia-zole ligand and two I atoms. In the crystal structure, adjacent mol-ecules are connected by π-π contacts between the thia-zole rings [centroid-centroid distance = 3.591 (3) Å].
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The asymmetric unit of the title compound, [HgBr(2)(C(8)H(8)N(2)S(2))], contains two crystallographically independent mol-ecules. The Hg(II) atoms are four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bi-1,3-thia-zole ligand and two Br atoms. In the crystal structure, inter-molecular C-H⋯Br hydrogen bonds and π-π contacts between the thia-zole rings ...
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In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bi-1,3-thia-zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter-chain C-H⋯Br hydrogen bonds and π-π contacts between the thia-zole rings [centroid...
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In the [Fe(4,4'-bit)(3)](2+) (4,4'-bit is 4,4'-bi-1,3-thia-zole) cation of the title compound, [Fe(C(6)H(4)N(2)S(2))(3)][FeBr(4)]Br, the Fe(II) atom (3 symmetry) is six-coordinated in a distorted octa-hedral geometry by six N atoms from three 4,4'-bit ligands. In the [FeBr(4)](-) anion, the Fe(III) atom (3 symmetry) is four-coordinated in a distorted tetra-hedral geometry. In the crystal, inter...
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